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JEE CHEMISTRY MCQ: CHEMICAL KINETICS

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For the reaction 2N2O5(g)→4NO2(g)+O2(g),2 \mathrm{N}_2 \mathrm{O}_5(\mathrm{g}) \rightarrow 4 \mathrm{NO}_2(\mathrm{g})+\mathrm{O}_2(\mathrm{g}), the concentration of NO2\mathrm{NO}_2 increases by 2.4×10−2M2.4 \times 10^{-2} \mathrm{M} in 6 s.6 \mathrm{~s}. What will be the average rate of appearance of NO2\mathrm{NO}_2 and the average rate of disappearance of N2O5?\mathrm{N}_2 \mathrm{O}_5?
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Correct option: D
4×10−3Ms−1,2×10−3Ms−14 \times 10^{-3} \mathrm{Ms}^{-1}, 2 \times 10^{-3} \mathrm{Ms}^{-1}
Option D (4×10−3Ms−1,2×10−3Ms−14 \times 10^{-3} \mathrm{Ms}^{-1}, 2 \times 10^{-3} \mathrm{Ms}^{-1}) is correct because the average rate of appearance of NO2 and disappearance of N2O5 are calculated based on the stoichiometry of the reaction.

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The reaction A2+B2→2AB\mathrm{A}_2+\mathrm{B}_2 \rightarrow 2 \mathrm{AB} follows the mechanism

A2⇌k−1k1A+A (fast) A+B2→k2AB+B (slow) A+B→AB (fast) \begin{aligned} & {{\text{A}}_2}\mathop \rightleftharpoons \limits_{{{\text{k}}_{ - 1}}}^{{{\text{k}}_1}} {\text{A}} + {\text{A (fast) }} \\ & \mathrm{A}+\mathrm{B}_2 \xrightarrow{\mathrm{k}_2} \mathrm{AB}+\mathrm{B} \text { (slow) } \\ & \mathrm{A}+\mathrm{B} \rightarrow \mathrm{AB} \text { (fast) } \end{aligned}

The overall order of the reaction is:
For the first order reaction with the rate constant kk, which expression gives the rate half-life period? (Initialconc.=a)(Initial\mathrm{ }conc.\mathrm{ } = a) Which of the following is a zero order reaction? For a certain reaction involving a single reactant, it is found that C0TC_0 \sqrt{T} is constant, where C0C_0 is the initial concentration of the reactant and TT is the half-life. What is the order of the reaction? Arrhenius equation is The energy of activation for an uncatalysed reaction is 100 kJ/mol.100 \mathrm{~kJ/mol}. Presence of a catalyst lowers the energy of activation by 75%75 \%. The log⁡10K2K1\log _{10} \frac{K_2}{K_1} of the ratio of rate constant of catalysed and uncatalysed reactions at 27∘C27^{\circ} \mathrm{C} is?

Assume the frequency factor is same for both reactions. (Given 2.303×8.314=19.1472.303 \times 8.314=19.147)
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