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NEET UG CHEMISTRY MCQ: SURFACE CHEMISTRY

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Application +4 | -1
Among the electrolytes Na2SO4,CaCl2,Al2(SO4)3ā€…ā€Šandā€…ā€ŠNH4Cl\mathrm{N}{\mathrm{a}_2}\mathrm{S}{\mathrm{O}_4}\mathrm{,CaC}{\mathrm{l}_2}\mathrm{,A}{\mathrm{l}_2}{\left( {\mathrm{S}{\mathrm{O}_4}} \right)_3}\;\mathrm{and}\;\mathrm{N}{\mathrm{H}_4}\mathrm{Cl}, the most effective coagulation agent for Sb2S3\mathrm{S}{\mathrm{b}_2}{\mathrm{S}_3} sol is
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Correct option: C
Al2(SO4)3\mathrm{A}{\mathrm{l}_2}{\left( {\mathrm{S}{\mathrm{O}_4}} \right)_3}
Option C (Al2(SO4)3\mathrm{A}{\mathrm{l}_2}{\left( {\mathrm{S}{\mathrm{O}_4}} \right)_3}) is correct because, according to the Hardy-Schulze rule, the ion with the highest charge will be the most effective in coagulating a sol. Since Sb2S3Sb_2S_3 is a negative sol, the cation with the highest charge (Al3+Al^{3+}) will be the most effective.

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