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NEET UG CHEMISTRY MCQ: HALOALKANES AND HALO ARENES

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Which of the following reaction(s) can be used for the preparation of alkyl halides?

i) CH3CH2OH+HCl→Anhyd.ZnCl2C{H_3}C{H_2}OH + HCl\xrightarrow{{\mathrm{Anhyd}\mathrm{.ZnC}{\mathrm{l}_2}}}

ii) CH3CH2OH+HCl→C{H_3}C{H_2}OH + HCl \to

iii) (CH3)3COH+HCl→{(C{H_3})_3}COH + HCl \to

iv) (CH3)2CHOH+HCl→Anhyd.ZnCl2{(C{H_3})_2}CHOH + HCl\xrightarrow{{\mathrm{Anhyd}\mathrm{.ZnC}{\mathrm{l}_2}}}
View answer and explanation
Correct option: C
I, III and IV only
Option C (I, III and IV only) is correct because primary, secondary, and tertiary alcohols can react with HCl to form alkyl halides, sometimes requiring a catalyst like anhydrous ZnCl2ZnCl_2.

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