JEE CHEMISTRY MCQ: CO-ORDINATION COMPOUNDS

1 Hard

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Analyzing +4 | -1

Identify the homoleptic complexes with odd number of d electrons in the central metal.

(A)

\left[\mathrm{FeO}_4\right]^{2-}

(B)

\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{3-}

(C)

\left[\mathrm{Fe}(\mathrm{CN})_5 \mathrm{NO}\right]^{2-}

(D)

\left[\mathrm{CoCl}_4\right]^{2-}

(E)

\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_3 \mathrm{F}_3\right]

Choose the correct answer from the options given below:

View answer and explanation

Correct option: A

(B) and (D) only

Option A ((B) and (D) only) is correct because only

\left[\mathrm{Fe}(\mathrm{CN})_6\right]^{3-}

and

\left[\mathrm{CoCl}_4\right]^{2-}

are homoleptic complexes with an odd number of d electrons in the central metal ion.

More Questions from CO-ORDINATION COMPOUNDS

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\mathrm{K}\left[ {\mathrm{Ag}{{\left( {\mathrm{CN}} \right)}_2}} \right]

\left[ {\mathrm{PtC}{\mathrm{l}_2}{{\left( {\mathrm{N}{\mathrm{H}_3}} \right)}_4}} \right]\mathrm{B}{\mathrm{r}_2}\mathrm{\;and\;}\left[ {\mathrm{PtB}{\mathrm{r}_2}{{\left( {\mathrm{N}{\mathrm{H}_3}} \right)}_4}} \right]\mathrm{C}{\mathrm{l}_2}\mathrm{\;}

\left[\mathrm{Pt}\left(\mathrm{NH}_3\right)_4 \mathrm{Cl}_2\right]\left[\mathrm{PtCl}_4\right]

\left[{Co}\left({NH}_3\right)_5\left({NO}_2\right)\right] {Cl}_2

\left[{Co}\left({NH}_3\right)_5({ONO})\right] {Cl}_2 \ldots \ldots \ldots

\left[{Cu}\left({NH}_3\right)_4\right]\left[{PtCl}_4\right] \,\, \& \,\, \left[{Pt}\left({NH}_3\right)_4\right]\left[{CuCl}_4\right] \ldots \ldots \ldots

\left[{Pt}\left({NH}_3\right)_4 {Cl}_2\right] {Br}_2 \, \, \& \, \, \left[{Pt}\left({NH}_3\right)_4 {Br}_2\right]{Cl}_2 \ldots \ldots \ldots