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JEE CHEMISTRY MCQ: S-BLOCK ELEMENTS

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Analyzing +4 | -1
(A)(A) is a ternary salt with divalent cation. (A)(A) gives yellow ppt. with K2CrO4\mathrm{K}_2 \mathrm{CrO}_4 as well as with AgNO3\mathrm{AgNO}_3. (A) is precipitated by H2 S\mathrm{H}_2 \mathrm{~S} neither in acidic nor ammoniacal medium, but addition of (NH4)2CO3\left(\mathrm{NH}_4\right)_2 \mathrm{CO}_3 in NH4OH\mathrm{NH}_4 \mathrm{OH} gave white ppt. (B). 0.297 g0.297 \mathrm{~g} of (A)(A) gave 0.197 g0.197 \mathrm{~g} of (B)(B). Identify (A)(A).
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Correct option: A
BaBr2\mathrm{BaBr}_2
The correct answer is A (BaBr2\mathrm{BaBr}_2) because it satisfies the given conditions of forming yellow precipitates with K2CrO4\mathrm{K}_2 \mathrm{CrO}_4 and AgNO3\mathrm{AgNO}_3, and forming a white precipitate with (NH4)2CO3(\mathrm{NH}_4)_2 \mathrm{CO}_3 in NH4OH\mathrm{NH}_4 \mathrm{OH}.

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